A homoleptic tetravalent cerium silylamide.
نویسندگان
چکیده
Treatment of Ce[N(SiHMe(2))(2)](3)(thf)(2) with the chlorinating agents PhICl(2), Ph(3)CCl or C(2)Cl(6) gave the homoleptic Ce(IV) silylamide Ce[N(SiHMe(2))(2)](4). When performed in the absence of donating (solvent) molecules, the trivalent cluster Ce(5)[N(SiHMe(2))(2)](8)Cl(7) was isolated.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 1 شماره
صفحات -
تاریخ انتشار 2013